Beilstein J. Org. Chem.2018,14, 2112–2124, doi:10.3762/bjoc.14.186
axle. In all the examined cases, the 1,2,3-alternate and cone atropoisomers are, respectively, the kinetic and the thermodynamic ones.
Keywords: atropoisomers; calixarene; conformation; pseudorotaxane; socialisomerism; Introduction
Mechanomolecules [1][2][3][4], such as rotaxanes and catenanes show
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Graphical Abstract
Figure 1:
Cartoon representation of the chiral rotaxane of the Goldup group [15,16] (I and I*) and of the chiral pse...